Ammonia, Carbon neutrality, Heavy-duty engine, Nitrogen Oxides, Reactivity controlled compression ignition (RCCI), Teknik, Maskinteknik, Energiteknik, Engineering and Technology, Mechanical Engineering, Energy Engineering

This paper examines the potential of using ammonia (NH 3) as a primary fuel in heavy-duty engines for decarbonization, with some challenges yet to be addressed. It presents a numerical study of a Reactivity Controlled Compression Ignition engine, where pilot diesel is used to ignite the premixed ammonia/air mixture. The numerical model and combustion mechanism are validated against engine experimental results using methanol and iso-octane fuels and ignition delay times of ammonia/n-heptane mixtures measured in a rapid compression machine. The findings show that the engine can effectively operate with up to 50% of the total energy supplied by premixed ammonia, albeit with slightly elevated NO emissions compared to a diesel-fueled engine. Increasing ammonia further leads to lower combustion efficiency. Hydrogen can be utilized in the ammonia engine to enhance ammonia combustion; however, NO emissions increase further. Ammonia leakage primarily originates from regions near the cold wall, the center of the cylinder, and the crevice. N 2 O mainly forms at the ammonia flame front. Emission of N 2 O is therefore mainly due to flame front quenching near the wall.