The Hercules kinematic group is a kinematic anomaly of stars observed in the solar neighbourhood (SNd). In this series of papers, we present a comprehensive study of this structure. This paper focuses on its chemical signatures over several groups of elements. The next paper discusses its kinematical properties. While studies suggested a non-native origin of Hercules stars due to the distinct chemical and kinematic features, previous studies focussed mainly on the Fe abundances. We adopt chemical data with abundances of elements from GALAH (Galactic Archaeology with HERMES) and APOGEE (Apache Point Observatory Galactic Evolution Experiment) to seek further chemical implications on the origin. Our analysis reveals that the low alpha population of the low angular momentum Hercules group is significantly enhanced in iron-peak (Fe, Ni, Mn) and Odd-Z (Na, Al) elements, and slightly deficient in alpha elements (O, Ca, Ti) compared to kinematically local stars. The super enhancement in iron-peak elements and deficiency in alpha elements support their origin from the outer thin bar in the inner Galaxy. Moreover, the enhancement in Na and Al indicates these stars as the youngest stars in the old sequence from the inner thick disc. Hence, the origin of these stars can be related to the outer bar region. These chemical signatures require the underlying dynamical mechanism that forms the Hercules group to be capable of transporting stars in the inner Galaxy out to the SNd. The next paper will consider the Trojan orbits as the favoured mechanism. [ABSTRACT FROM AUTHOR]

Copyright of Monthly Notices of the Royal Astronomical Society is the property of Oxford University Press / USA and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)