Abstract One of the most important environmental challenges that needs to be resolved is the industrial discharge of synthetic dyes. Graphitic carbon nitride (g-C3N4), Titanium dioxide (TiO2) and flower-like copper oxide (CuO)/copper cobaltite (CuCo2O4) nanocomposites were synthesized in order to synthesis an effective visible light driven photocatalyst that could degrade Rhodamin B (Rh.B) dye under simulated solar light irradiation. The SEM and TEM results verifies that the flower-like CuO/CuCo2O4 (CCO) structure and g-C3N4/TiO2 (g-CN/TO) generated a smart hybrid structure with superior g-CN distribution. According to the photocatalytic studies, g- C3N4/TiO2/CuO/CuCo2O4 (g-CN/TO/CCO) shows good photodegradation of Rh.B dye (99.9%) in minmal times (1 h) in CCO: g-CN/TO (2:1) ratio by Z-Scheme mechanism. The enhanced visible light absorption and effective electron-hole pair separation provided by the synergistic dispersion of CuO/CuCo2O4 and g-C3N4 can be attributed to the improved photocatalytic performances. These novel insights into g-CN/TO/CCO based photocatalysts are useful for treating industrial effluent.