Process integration, LNG vessel, CO2 capture, Organic rankine cycle, Technology assessment, Renewable energy sources, TJ807-830, Environmental engineering, TA170-171

The pressing need to significantly reduce global CO2 emissions requires the decarbonization of the shipping industry. Currently, shipping relies on fossil fuels with a shift from heavy oil to liquefied natural gas. The main engine is the primary energy user onboard vessels, and its exhaust is the main CO2 emission source. A potential path to reduce emissions onboard vessels is the capture, compression, and storage of CO2 from the exhaust gases. This requires effective integration across the engine, the capture technology, the CO2 compression, cooling, and storage. The integration of four alternative capture technology options is conceptually explored and assessed: chemical absorption, membranes, temperature swing adsorption, and cryogenic distillation. Integration schemes are developed for each of the four technologies that achieve carbon capture, compression, and storage driven by the exhaust gas waste heat as the only energy source. Heat and power requirements are met through heat integration and heat-to-power conversions using organic Rankine cycles (ORCs). The study was performed on an LNG vessel using LNG fuel in its main engine. Thermal capture technologies (absorption and adsorption) are observed to significantly outperform their alternatives (membranes and cryogenic distillation) and capture, compress, and store more than twice the amount of CO2 emissions from the engine exhaust stream. Finally, the proposed integration schemes resulted in self-sustainable onboard capture systems without combusting additional fuel.